It depends on what the NAS supports for RAID expansion. If you start with a minimum three-drive RAID 5, adding a fourth drive will add additional volume capacity.
But if you have an N drive NAS and replace one of the drives with a larger-capacity drive, the volume size doesn't change. You need to swap out all the drives (one at a time and wait for a volume rebuild each time) with larger capacity drives before you get a larger volume.
Keep in mind that if a drive fails during the expansion, you'll probably lose the volume. But that's ok, since you'll have a backup on another device any way, right?