I was writing a more detailed answer, but ran out of time. If you want the real details, reply back and i'll work on something.
Nutshell: You're used to an "All-In-One" device and now you've split it into pieces. At which point, you need to understand the pieces or you'll have a mess (like this).
1. When you connect using only your ADSL Modem + Router ONLY, what IP address is reported as it's WAN IP? Not the one your PC gets from DHCP, but what it itself reports as the WAN IP assigned to its PPPoA interface. You'll have to login to the modem to see this. Getting it from 'what is my IP address' websites won't give you the answer I'm looking for. Point in asking this is only to make sure that your ISP isn't using private address space on its WAN and then doing the translations someplace else as that'll throw off the whole rest of my answer.
I'm going to assume for now that it's giving you a registered IP address (something not in 192.168, 172.16-172.31, 10 space).
2. If you've chained the WAN link of your ASUS router to the LAN link of your ADSL+ Modem, and it's getting an address AT ALL without configuration, much less one that's in the 192.168, 172.16-31, or 10 space, it's very likely you didn't properly put the modem in bridge mode. Double check it. You'll know you did it because you'll think you just broke everything if you go back to using it as a normal ADSL Modem again.
3. The reason why you don't see VPI/VCI in the ASUS is because it's an Ethernet router, not an ATM router. That's why you have to have the ADSL Modem there. VPI/VCI is an ATM construct, and therefore, it is configured on the ADSL Modem. Once it's in bridge mode., it's probably the only configuration it'll ask for.
4. The reason why you don't see PPPoA on the ASUS is because, once again, it's an Ethernet router, not an ATM router. That's where the A in PPPoA comes from. Instead, if the ADSL modem is in fact in bridge mode, and you've connected its LAN port to the WAN port of your ASUS router, then you need to setup your ASUS router for PPPoE (since it's now being done over Ethernet). That'll then get sent over the Ethernet WAN interface on the ASUS, over to the ADSL router on its Ethernet LAN port, at which point, it'll get bridged over to the ATM port (its WAN port on DSL) and on to the ISP.
So now, you'll put in any PPP information the ASUS and it should connect. If it doesn't, there may be one other thing going on, and that's that the ISP may be 'MAC Locking' where it'll accept PPP connections from. If that's the case, you'll need to get the MAC address off of the ADSL modem and plug it in on the ASUS where it lets you do a WAN MAC Override. It's usually stamped on the bottom of the device but not always and not always the right one. Worst case, if you at least get this far, you may be able to call your ISP and see if they can reset it to your ASUSs MAC address.
At this point, you've now successfully split up the 'All-In-One' device into its components with the ASUS now handling the Layer 3 stuff.
The misconfiguration message should now be gone since the ADSL modem is now not trying to also do the functions you've moved to the ASUS device.