I've never seen a Gigabit Ethernet SFP for plastic. There have been 100Mbit ones, but they don't seem to be very common, and thus have a higher price than regular fiber SFP's. Plus you run into both the vendor lock-in issue and the low level of support for 100Mbit SFPs in general.
There is an IEEE
study group for Gigabit Ethernet over POF, but there isn't even a timetable for producing a draft.
I don't see a good usage case for it - based on the status of Gigabit Ethernet over it, faster speeds (be they 2.5, 5, or 10GbE) seem to be
very far off (if even possible). It is going to be more expensive than copper, if for no other reason than copper being ubiquitous, while support for
any fiber is unusual in low-end switches and even "prosumer" type switches typically only support 1 to 4 SFP ports. Regular glass fiber is not as fragile as people think it is (I've given demonstrations of rolling over "zip cord" type fiber with an occupied office chair, tying it in knots, playing tug-of-war, and so on).
One of the proposed benefits of POF is ease of termination -
OptoLock is similar to the back-wire option on electrical receptacles (cut wire and shove into hole) but I'm not sure how will that will work in the field with non-professional termination, particularly at GigE speeds. I used to make my own fiber cables (both single mode and multimode) but cables are now available at such a low cost (the whole cable assembly with connectors costs less than I'd pay for a single connector) that it isn't worth it.
TOSLINK has used plastic fiber, but in short (15' or less) cables at low bitrates.