I haven't had any outbound traffic blocked by skynet from any of my devices yet to compare, but I'm noticing similar errors in pi-hole (on an internal Linux server). All my devices have manual IPs and some domains defined in LAN>DHCP, but these are getting mixed up somewhere along the line. I'm seeing MAC addresses for IoT devices on a VLAN used for devices like my server on the main (wired) network.
I don't think this is directly caused by skynet. What you're seeing
@custmblt is likely just a symptom of something else - something serious but not yet identified.